Temperature-dependent Kinetics on Laser Induced Photolysis of Aqueous CS_2-HONO Solutions

作     者：Hao Jie FANG Cheng Zhu ZHU Wen Bo DONG Hui Qi HOU 

作者机构：Environment Science Institute Fudan University Shanghai 200433 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2005年第16卷第10期

页      面：1364-1366页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 0703[理学-化学] 

主　　题：CS2OH CS2OH-HONO activation energy laser photolysis/transient absorption. 

摘      要：A laser photolysis/transient absorption technique has been employed to investigate the photolysis kinetics of aqueous CS2-HONO solutions at 355 nm. Spectral analysis shows that CS2OH will react with HONO to form CS2OH-HONO. Temperature dependent rate coefficients for the reaction are reported for the first time. The following Arrhenius expressions adequately summarize the kinetic data obtained over the temperature range 273-313 K （units are L·mol^-1·s^-1）： In k = （31.6±0.6）-{（4.1±0.2）×10^3/T}, and the activation energy in unit of *** is 32.47 with the temperature accuracy 0.2 K.