Synthesis and Characterization of Novel Polyimides Based on Pyridine-containing Diamine

作     者：Shu Jiang ZHANG Yan Feng LI Xiao Long WANG Da Xue YIN Yu SHAO Xin ZHAO 

作者机构：College of Chemistry and Chemical Engineering State Key Laboratory of AppliedOrganic Chemistry Institute of Biochemical Engineering ＆ Environmental Technology Lanzhou University Lanzhou 730000 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2005年第16卷第9期

页      面：1165-1168页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Heteroaromatic polymer polyimides pyridine-containing monomer synthesis,aromatic diamine. 

摘      要：A new aromatic diamine monomer containing pyridine unit, 2,6-bis （4-aminophenoxy- 4＇-benzoyl）pyridine（BABP）, was synthesized in three steps, starting from 2,6-pyridinedicarboxyl chloride. A series of novel pyridine-containing polyimides were prepared v/a the polycondensation of BABP with various aromatic dianhydrides through poly（amic acid） precursors, and thermal or chemical imidization of the precursors. The polyimides exhibit desirable properties, e.g., good solubility in N-methyl-2-pyrrolidone and m-cresol, excellent thermal stability and film-forming capability, as well as high inherent viscosity, indicating high molecular weight.