Chlorine-radical Induced Oxidation of Glyoxal and Glyoxal-S(IV) Adducts in the Aqueous Phase

作     者：YingLI YunTANG JiaQiangWANG 

作者机构：DepartmentofAppliedChemistryYunnanUniversityKunming650091／／DepartmentofChemistryHongheCollegeMengzi661100 YunnanJiehuaChemGroupCo.Ltd.Kaiyuan661600 DepartmentofAppliedChemistryYunnanUniversityKunming650091 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2005年第16卷第1期

页      面：119-122页

核心收录：

学科分类：07[理学] 070602[理学-大气物理学与大气环境] 0706[理学-大气科学] 0703[理学-化学] 

基　　金：云南大学校科研和教改项目(2002Z002GC) 云南省自然科学基金(2003E0007R ,2003E0004Q) 

主　　题：Chlorine-radical glyoxal glyoxal mono- and dibisulfite adducts aqueous phase rate constants. 

摘      要：A laser flash photolysis study of the reactivity of Cl˙with glyoxal, glyoxal mono- and dibisulfite adducts, 1-hydroxy-2, 2-diol-ethanesulfonate and 1, 2-dihydroxy-1, 2-ethanedi sulfonate in the aqueous phase was carried out. The obtained rate constants can be used for atmospheric modeling.