Nitrogen doped porous carbon-based bifunctional oxygen electrocatalyst with controllable phosphorus content for zinc-air battery
作者机构：School of Material Science and EngineeringHenan University of TechnologyZhengzhou 450001China Foshan Xianhu Laboratory of the Advanced Energy Science and TechnologyGuangdong LaboratoryXianhu Hydrogen ValleyFoshan 528200China State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan 430070China Department of Applied Physics and Institution of Energy and MicrostructureNanjing University of Science and TechnologyNanjing 210094China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2023年第16卷第4期
页 面：5887-5893页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金：supported by the Henan Province Education Department Natural Science Research Item(No.21A480005) the Research Project at School-level of Henan University of Technology(No.2020BS017)
主 题：cobalt-nitrogen doped porous carbon phosphorus doping bifunctional electrocatalyst oxygen reduction reaction(ORR)and oxygen evolution reaction(OER) Zn-air battery
摘 要：The controllable construction of non-noble metal based bifunctional catalysts with high activities towards oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is of great significance,but remains a ***,we reported an effective method to synthesize cobalt-nitrogen doped mesoporous carbon-based bifunctional oxygen electrocatalyst with controllable phosphorus content(Co-N-P_(X)-MC,X=0.5,1.0,1.5,2.0).The mesoporous carbon substrate endowed the asprepared samples with more exposed active surface(236.50 m^(2)·g^(−1))and the most appropriate doping ratio of phosphorus had been investigated to be 1.5(Co-N-P1.5-MC).For ORR,Co-N-P1.5-MC exhibited excellent catalytic activity with more positive onset potential(1.01 V)and half-wave potential(0.84 V)than the other *** OER,Co-N-P1.5-MC also showed a low overpotential of 415 *** experimental results and density-functional theory(DFT)calculations,the outstanding bifunctional catalytic performance of Co-N-P1.5-MC was due to the synergistic cooperation between the P and N dopants,which could reduce the reaction barriers and was favorable for ORR and ***,the Zn-air battery using Co-N-P1.5-MC as the cathode showed remarkable battery performance with high stability(could operate stably for over 160 h at 10 mA·cm^(−2))and maximum power density(119 mW·cm^(−2)),demonstrating its potential for practical *** work could provide significant enlightenment towards the design and construction of bifunctional oxygen electrocatalyst for next-generation electrochemical devices.
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