A novel Cu_(1.5)Mn_(1.5)O_(4)photothermal catalyst with boosted surface lattice oxygen activation for efficiently photothermal mineralization of toluene
作者机构：Shenzhen Research InstituteHubei Key Laboratory of Mineral Resources Processing and EnvironmentState Key Laboratory of Silicate Materials for ArchitecturesWuhan University of TechnologyWuhan 430070China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2023年第16卷第2期
页 面：2133-2141页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金：supported by Science and Technology Planning Project of Shenzhen Municipality(No.JCYJ20200109150225155) the National Natural Science Foundation of China(NSFC,No.92163125)
主 题：Cu_(1.5)Mn_(1.5)O_(4)nanomaterial surface lattice oxygen light-driven photothermal catalysis volatile organic compounds
摘 要：Developing a novel photothermal catalyst for efficient mineralization of volatile organic compounds(VOCs)is of great significance to control air ***,for the first-time,a spinel Cu_(1.5)Mn_(1.5)O_(4)nanomaterial with enhanced surface lattice oxygen activation was successfully obtained by a novel light-driven in situ reconstruction strategy from its precursor(CuMnO_(2))for efficient toluene mineralization.X-ray diffraction(XRD)and high-resolution transmission electron microscopy(HRTEM)analyses confirm that the CuMnO_(2)phase was converted into spinel Cu1.5Mn1.5O4 phase under full spectrum light ***–visible–near infrared ray(UV–vis–NIR)spectroscopy,X-ray photoelectron spectroscopy(XPS)analysis,and density functional theory(DFT)calculations determine that the strong near-infrared absorption ability and low dissociation energy of oxygen bond in Cu_(1.5)Mn_(1.5)O_(4)are beneficial to its surface lattice oxygen ***,O2-temperature programmed desorption(TPD)and in situ diffuse reflectance infrared transform spectroscopy(DRIFTS)further indicate that the surface lattice oxygen of the Cu_(1.5)Mn_(1.5)O_(4)is easily activated under light irradiation,which can promote ring opening of *** research endows a new design of photothermal nanomaterial with enhanced lattice oxygen activation for deep oxidation of VOCs.
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