Luminescent nanoparticle-arrays synthesized via polymer pen lithography
作者机构：Institute of Advanced MaterialsJiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)Nanjing Tech UniversityNanjing 211816China Centre for Optical and Electromagnetic ResearchGuangdong Provincial Key Laboratory of Optical Information Materials and TechnologyNational Centre for International Research on Green OptoelectronicsSouth China Academy of Advanced OptoelectronicsSouth China Normal UniversityGuangzhou 510006China College of ChemistryState Key Laboratory of the Chemistry and Utilization of Carbon Based EnergiesXinjiang UniversityUrumqi 830046China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2023年第16卷第2期
页 面：3125-3129页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学]
基 金：supported by the Major Research Program Cultivation Project of National Science Foundation of China(No.91956107) the National Natural Science Foundation of China(Nos.2201101389,21871137,62122028,and 11974123)
主 题：polymer pen lithography upconversion luminescence nanoparticle array ligand
摘 要：We report a high-throughput approach to generating lanthanide-doped upconversion nanoparticle(UCNP)arrays through polymer pen lithography(PPL),where instead of the expensive block co-polymer,two types of polymers are employed with one working as ink carrier,e.g.,polyethylene glycol-400(PEG-400)to facilitate smooth transfer from the tip to the substrate and the other,e.g.,polyvinyl pyrrolidone(PVP),as chelator to ensure successful patterning of metal *** strong coordination of PVP with rare earth ions(RE^(3+))is the key for weakening the interaction between RE3+ions and the carrier PEG-400 so that the good mobility of ink can be *** experimental results have shown that besides PVP,small molecules with functional groups that can coordinate with RE^(3+)ions,such as oleic acid,can also serve the same role as PVP,which greatly enriches the ink library for *** 1 cm^(2)area arrays comprising individual UCNP can be reliably generated with characteristic upconversion *** strategy not only allows reliable production of individual UCNP arrays,it also paves new avenue to the precise synthesis of multifunctional NPs for lasing,imaging,encryption,and anticounterfeiting.
维普期刊数据库