Magnetic molecular materials with paramagnetic lanthanide ions
Magnetic molecular materials with paramagnetic lanthanide ions作者机构:Beijing National Laboratory for Molecular SciencesState Key Laboratory of Rare Earth Materials Chemistry and ApplicationsCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China
出 版 物:《Science China Chemistry》 (中国科学(化学英文版))
年 卷 期:2009年第52卷第11期
页 面:1739-1758页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
基 金:Supported by the National Natural Science Foundation of China (Grant Nos. 20821091, 20503001) the National Basic Research Program of China (Grant Nos. 2006CB601102, 2009CB929403)
主 题:lanthanide coordination compound magnetic coupling magnetic ordering magnetic relaxation single-molecule magnet single-chain magnet single-ion magnet
摘 要:The diverse magnetic properties of lanthanide-based magnetic molecular materials are introduced in the following ***,the general aspects of magnetic molecular materials and electronic states of lanthanide ions are *** the structures and magnetic properties are described and analyzed for molecules with one lanthanide ion,4f-4f,4f-3d and 4f-p magnetic coupling *** each section,magnetic coupling,magnetic ordering and magnetic relaxation phenomenon are briefly reviewed using some ***,some possibilities of developing magnetic molecular materials containing lanthanide ions are discussed in the outlook part.