Carbonized waste milk powders as cathodes for stable lithium-sulfur batteries with ultra-large capacity and high initial coulombic efficiency

作     者：Rabia Khatoon Sanam Attique Rumin Liu Sajid Rauf Nasir Ali Luhong Zhang Yu-Jia Zeng Yichuan Guo Yusuf Valentino Kaneti Jongbeom Na Haichao Tang Hongwen Chen Yang Tian Jianguo Lu Rabia Khatoon;Sanam Attique;Rumin Liu;Sajid Rauf;Nasir Ali;Luhong Zhang;Yu-Jia Zeng;Yichuan Guo;Yusuf Valentino Kaneti;Jongbeom Na;Haichao Tang;Hongwen Chen;Yang Tian;Jianguo Lu

作者机构：State Key Laboratory of Silicon MaterialsKey Laboratory for Biomedical Engineering of Ministry of EducationSchool of Materials Science and EngineeringZhejiang UniversityHangzhou310027China Institute for Composites Science InnovationSchool of Materials Science and EngineeringZhejiang UniversityHangzhou310027China Hubei Collaborative Innovation Centre for Advanced Organic Chemical MaterialsFaculty of Physics and Electronic ScienceHubei UniversityWuhanHubei430062China State Key Laboratory for Silicon MaterialsKey Laboratory of Quantum Technology and DevicesDepartment of PhysicsZhejiang UniversityHangzhou310027China College of Physics and Optoelectronic EngineeringShenzhen UniversityShenzhen518060China International Center for Materials Nanoarchitectonics(WPI-MANA)National Institute for Materials Science(NIMS)1-1NamikiIbaraki305-0044Japan School of Chemical Engineering&Australian Institute for Bioengineering and Nanotechnology(AIBN)The University of QueenslandBrisbaneQLD4072Australia 

出 版 物：《Green Energy & Environment》 (绿色能源与环境（英文版）)

年 卷 期：2022年第7卷第5期

页      面：1071-1083页

核心收录：

学科分类：0830[工学-环境科学与工程（可授工学、理学、农学学位）] 0808[工学-电气工程] 08[工学] 0807[工学-动力工程及工程热物理] 

基　　金：supported by Innovation Platform of Energy Storage Engineering and New Material in Zhejiang University (K19-534202-002) Provincial Innovation Team on Hydrogen Electric Hybrid Power Systems in Zhejiang Province Shenzhen Science and Technology Project (JCYJ20170412105400428)。 

主　　题：composites powders initial 

摘      要：To explore the natural resources as sustainable precursors offers a family of green materials.The use of bio-waste precursors especially the remaining from food processing is a scalable,highly abundant,and cost-effective strategy.Exploring waste materials is highly important especially for new materials discovery in emerging energy storage technologies such as lithium sulfur batteries(LSBs).Herein,waste milk powder is carbonized and constructed as the sulfur host with the hollow micro-/mesoporous framework,and the resulting carbonized milk powder and sulfur(CMP/S) composites are employed as cathodes for LSBs.It is revealed that the hollow micro-/mesoporous CMP/S framework can not only accommodate the volume expansion but also endow smooth pathways for the fast diffusion of electrons and Li-ions,leading to both high capacity and long cycling stability.The CMP/S composite electrode with 56 wt% loaded sulfur exhibits a remarkable initial capacity of 1596 mAh g^(-1) at 0.1 C,corresponding to 95% of the theoretical capacity.Even at a rate of 1 C,it maintains a high capacity of 730 mAh g^(-1) with a capacity retention of 72.6% after 500 cycles,demonstrating a very low capacity fading of only 0.05% per cycle.Importantly,the Coulombic efficiency is always higher than 96%during all the cycles.The only used source material is expired waste milk powders in our proposal.We believe that this trash to treasure approach will open up a new way for the utilization of waste material as environmentally safe and high performance electrodes for advanced LSBs.