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Relation Between Crystal Structure and Liquid Crystallinity of Ferrocene Derivatives

Relation Between Crystal Structure and Liquid Crystallinity of Ferrocene Derivatives

作     者:N.Nakamura 

作者机构:Department of Applied ChemistryRitsumeikan University Kusatsu 525-8577Japan 

出 版 物:《复旦学报(自然科学版)》 (Journal of Fudan University:Natural Science)

年 卷 期:2007年第46卷第5期

页      面:735-736页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主  题:ferrocene derivative crystal structure liquid crystal 

摘      要:1 Results In order to obtain liquid crystals including an ion atom as a transition metal, the ferrocene derivatives containing mesogenic group were designed with a view to prevent great bulk of ferrocenyl moiety in the molecules, because rod-like molecular shape is preferable to show liquid crystallinity. Therefore, methylene chain was installed as a flexible spacer between ferocenyl moiety and mesogenic one. As a result, a lot of liquid crystalline ferrocene derivatives were synthesized successfully. Si...

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