Constructing 0D/1D Ag3PO4/TiO_(2) S-scheme heterojunction for efficient photodegradation and oxygen evolution

作     者：Yukun Zhu Yan Zhuang Lele Wang Hua Tang Xianfeng Meng Xilin She 朱玉坤;庄严;王乐乐;唐华;孟献丰;佘希林

作者机构：School of Environmental Science and EngineeringQingdao UniversityQingdao 266071ShandongChina School of Materials Science&EngineeringJiangsu UniversityZhenjiang 212013JiangsuChina 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2022年第43卷第10期

页      面：2558-2568页

核心收录：

学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：国家自然科学基金(21975110) 山东省泰山青年学者计划 

主　　题：S-Scheme heterojunction 0D/1D Ag_(3)PO_(4)/TiO_(2) Oxygen production Photocatalytic degradation 

摘      要：An S-scheme heterojunction photocatalyst is capable of boosting photogenerated carrier separation and transfer,thus maintaining high photooxidation and photoredox ***,a 0D Ag_(3)PO_(4) nanoparticles(NPs)/1D TiO_(2) nanofibers(NFs)S-scheme heterojunction with intimate interfacial contact was designed via the the hydro-thermal *** from the abundant hydroxyl groups and size confinement effect of TiO_(2) NFs,the average diameter of the Ag_(3)PO_(4) nanoparticles decreased from 100 to 22 nm,which favored the construction of a 0D/1D geometry *** multifunctional Ag_(3)PO_(4)/TiO_(2) sample exhibited excellent photocatalytic activity and stability in photocatalytic oxygen production(726μmol/g/h)and photocatalytic degradation of various organic contaminants such as rhodamine B(100%),phenol(60%)and tetracycline hydrochloride(100%).The significant improvements in the photocatalytic performance and stability can be attributed to the intimate interfacial contacts and rich active sites of 0D/1D geometry,fast charge carrier migration,and outstanding photoredox properties induced by the S-scheme charge-transfer *** work offers a promising strategy for constructing 0D/1D S-scheme heterojunction photocatalysts for improved photocatalytic performance.