Studies on the Redox Properties of Rare Earth Heteropoly Tungstoarsenate K_17[Ln(As_2W_17O_61)_2]·xH_2O

作     者：LIU Jing-fu, WANG Guang and ZHAO Ben-liang (Department of Chemistry, Northeast Normal University, Changchun, 130024) 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：1993年第9卷第3期

页      面：175-180页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：Supported by the foundation of laboratory of rare earth chemistry and physics 

主　　题：Lanthanide heteropolytungstate Redox property Heteropolyanion 

摘      要：The redox properties of K17[Ln(As2W17O61)2](Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Tm or Yb) in solution were investigated using polarographic and cyclic voltammographic methods. Experimental results indicate that the heteropolyanions underwent three-step-two-electron-tungsten-reduction processes, and each reduction process was accompanied by adding two protons.