SELECTIVE　OXYGENATION　OF　CYCLOHEXENE　WITH　DIOXYGEN　USING　POLYOXOMETALATE　INTERCALATED　LAYERED　DOUBLE　HYDROXIDES

作     者：Guo, J Jiao, QZ Xiong, G Lu, HJ Jiang, DZ Min, EZ 

作者机构：JILIN UNIV DEPT CHEM CHANGCHUN 130023 PEOPLES R CHINA RES INST PETR PROC BEIJING 100083 PEOPLES R CHINA 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1996年第7卷第6期

页      面：531-534页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：OXIDATION PRECURSORS HYDROTALCITE EPOXIDATION CATALYSTS 

摘      要：Cyclobexene was seleetively oxidized with dioxygeh by polyoxometalateintercalated layered double hydroxides to Produce 2-eyelobexene-one and2-ctclobexene-0 1undet mi id reaction *** talate p i I fared I ale red doub ie hydrox ideB (POa-LDHB) ate a newc lass of catalyt ic mater ial s deve loged in fecent yearB 11- 3]. *** it UBe as catalyBts bas not been we I I developed. Recent ly, M. A. Drezdzon teFor ted that the V,.0.:- and Mo.0::- an ions F if fared *** arefound to be effect ive catalyBts for convers ion of 2-Propanol and delydtogenat ion of butylethylbenzene [4]. Pinnavaia has noted that the BVW,,0.;SiV.W.0.;--, and 11.W,.0.g- an ionB intetcalated *** are b igh ly act ivecatalyBts for pbotocatal yi ic oxidat ion of isopropanol to acetone 15]. *** and co-workers have demonstrated that some POa intercalated bydroxi6es slow good catalyt ic act ivi t ies for the sbage Be feet ive eFoxidation of alienes with H:0. aB oxidant [6]. Recently, Xu laB found that someLDHs and tleit POa intercalates are highly active catalysts fot tie alkylation of butene with isobutane 171. The studieB of these mater ials ihcatalyt ic oxidat ion, however, have rece tved I lit ie attent *** oxi6at ion of organic substrates wi th molecu far oxygen is very attract ive from the v iewgoint of induBtr ial technology and synthet ic organ icchemistry & nice molecular oxygen is cheap, env ironmental ly c lean and eaBy to handle IS]. I t bas been known that many trans it ion me tal compounds,l the metal loporpbyr ins 191, organome ta I I ic compounds 110] 1 and po lyoxome talates 111] t etc. j have been use6 fot sc feet ive oxidat ion of alkenes andalkanes with moleculat oxygen. However, tlete is no regott on the : TIts lroject,.s sugported by the *** ion of lydrocarbons kith diolygen us lug LDHS and tie it POa intercalateB. In our pie, ionB,otk,,e la,e demonBttated tlat some LDH exb fo itgood catalyt ic act l, it tea for oxldat ion of eye lolexene wi t