Electrochemical Rhodium-Catalyzed Enantioselective C–H Annulation with Alkynes

作     者：Yuan-Qiong Huang Zhi-Jie Wu Li Zhu Qing Gu Xiaojie Lu Shu-Li You Tian-Sheng Mei 

作者机构：State Key Laboratory of Organometallic ChemistryCenter for Excellence in Molecular SynthesisShanghai Institute of Organic ChemistryUniversity of Chinese Academy of SciencesChinese Academy of SciencesShanghai 200032 State Key Laboratory of Drug ResearchShanghai Institute of Materia MedicaChinese Academy of SciencesPudongShanghai 201203 

出 版 物：《CCS Chemistry》 (中国化学会会刊（英文）)

年 卷 期：2022年第4卷第9期

页      面：3181-3189页

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：grant fromNSFC(nos.21821002,21772222,and 91956112),CAS(no.XDB20000000) Science and Technology Commission of Shanghai Municipality(nos.18JC1415600 and 20JC1417100) 

主　　题：organic electrochemistry enantioselective C–H annulation rhodium catalysis chiral spiropyrazolones C–H functionalization 

摘      要：The synergistic use of transition metal catalysis and electrochemistry is an attractive strategy for oxidative site-selective C–H functionalization since the use of stoichiometric chemical oxidants can be avoided and novel reactivity can be ***,metalcatalyzed electrochemical C–H functionalization is mainly limited to arene C(sp^(2))–Hfunctionalization,and enantioselective C–H functionalization is uncommon and remains challenging.