Photocatalytic Methane Conversion:Insight into the Mechanism of C(sp^(3))-H Bond Activation

作     者：Yuheng Jiang Yingying Fan Siyang Li Zhiyong Tang Yuheng Jiang;Yingying Fan;Siyang Li;Zhiyong Tang

作者机构：Chinese Academy of Science(CAS)Key Laboratory of Nanosystem and Hierarchy FabricationCAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing 100190 Center for Advanced Analytical ScienceSchool of Chemistry and Chemical EngineeringSchool of Civil EngineeringAnalytical and Testing CenterGuangzhou UniversityGuangzhou 510006 Center for Nanoscale Science and TechnologyAcademy for Advanced Interdisciplinary StudiesPeking UniversityBeijing 100871 University of Chinese Academy of SciencesBeijing 100049 

出 版 物：《CCS Chemistry》 (中国化学会会刊（英文）)

年 卷 期：2023年第5卷第1期

页      面：30-54页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：The authors acknowledge financial support from the Strategic Priority Research Program of Chinese Academy of Sciences(no.XDB36000000,Z.Y.T.) National Key Basic Research Program of China(no.2021YFA1200302,Z.Y.T.) National Natural Science Foundation of China(nos.92056204,21890381,and 21721002,Z.Y.T.) Guangdong Basic and Applied Basic Research Foundation,China(no.2021A1515110705,Y.Y.F.) On-campus Scientifc Research Project of Guangzhou University(no.RQ2021010,Y.Y.F.) 

主　　题：photocatalysis methane C-H bonds radical active site 

摘      要：Mild and direct conversion of methane into high value-added products is a desired goal for chemistry,energy,and *** active species generated in the photocatalytic reaction system under mild conditions activate the inert C-H bond in methane and promote methane *** review focuses on the developed mechanisms for C(sp^(3))-H bond activation in photocatalytic methane conversion,including radical and active site *** emphasis is placed on the detailed summary of mechanism,characterization method,and corresponding application in photocatalytic methane *** also discuss the challenges and prospects for future direction on C(sp^(3))-H bond activation mechanism in photocatalytic methane *** review aims to promote the development of photocatalytic methane conversion and provides guidance for the design of high-efficiency photocatalysts.