Association of a terpyridine ligand with lanthanide and copper(Ⅱ) nitrates

作     者：Monika Waesa-Chorab Adam Gorczyński Dariusz Marcinkowski Maciej Kubicki Violetta Patroniak 

作者机构：Faculty of ChemistryAdam Mickiewicz University 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2010年第28卷第S1期

页      面：61-65页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：Project support by the Polish Ministry of Higher Education and Science (NN 204 2716 33) 

主　　题：H-bonding copper(Ⅱ) lanthanides self-assembly terpyridine rare earths 

摘      要：Reactions between the 1,3-bis(6-methylpyridin-2-yl) pyridine ligand L,C17H15N3 and LnIII(1a,1b,1c,1d) or a mixture of LnIII and CuII nitrates(2a,2b,2c,2d) resulted in a series of respectively novel mono-and heterodinuclea r complexes,where LnIII=Sm(a) ,Eu(b) ,Tb(c) ,Dy(d) . The compounds were char acterized by elemental analysis,ESI-MS and IR spectra,furthermore we obtained crystals of [H2L][Eu(NO3) 5](1b) and [CuL2][Eu(NO3) 5](2b) suitable for XRD char acterization. In the crystal structures the Eu ions are 10-coordinated with quit e a narrow range of Eu-O distances which are between 0.2436 and 0.2556 nm. In 1b the ligand molecule is protonated in both terminal rings,and the N-H groups ar e involved in the N-H…O hydrogen bonds with the same oxygen atom of one of the nitro groups. These hydrogen bonds connect the ions in 1b into the complex which is the principal building block of the structure. In 2b the [CuL2]2+ counterion s are present;the Cu is octahedrally coordinated by all nitrogen iatoms of two L molecules which are therefore almost perpendicular to each other. The electros tatic interactions between the charged species are in both cases the main drivin g force of the crystal packing.