A Novel Magnetic Carbon Based Catalyst Synthesized from Reed Straw and Electric Furnace Dust for Biodiesel Production
作者机构:College of Metallurgy and EnergyNorth China University of Science and TechnologyTangshan063210China Qian’an CollegeNorth China University of Science and TechnologyQian’an064400China
出 版 物:《Journal of Renewable Materials》 (可再生材料杂志(英文))
年 卷 期:2022年第10卷第8期
页 面:2099-2115页
核心收录:
学科分类:07[理学] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学] 0702[理学-物理学]
基 金:the financial support from National Natural Science Foundation of China(Nos:52004095,51704119,and 21878161) the Natural Science Foundation of Hebei Province(E2017209243) Department of Education of Hebei Province(BJ2019038).
主 题:Reed biochar electric furnace dust magnetic biochar catalyst biodiesel environmental protection
摘 要:In the era of serious greenhouse gas emission and energy shortage,it is necessary to use solid waste to prepare new renewable materials.In this work,the potential application of reed straw and electric furnace dust was explored.Firstly,magnetic carbon carrier(EFD&C)was prepared by high temperature calcination,and then magnetic carbon catalyst(SM@EFD&C)was prepared by activation of sodium methoxide.The catalyst was used to prepare biodiesel by transesterification reaction to test its activity and stability.Reed biochar,EFD&C and SM@EFD&C were detected by Diffraction of X-rays(XRD),Fourier transform infrared(FT-IR),Inductively coupled plasma(ICP),Scanning electron microscope(SEM),Transmission electron microscope(TEM),Brunauer-Emmett-Teller(BET),Vibrating sample magnetometer(VSM),Temperature programmed desorption of CO_(2)(CO_(2)-TPD)and Thermogravimetric analysis(TG-DTG).The results showed that SM@EFD&C catalyst had some characteristics including porous structure,easy adsorption and better magnetism.Under the reaction conditions of 65℃for 2 h with 6 wt%catalyst and methanol/oil molar ratio of 15:1,the biodiesel yields from reed biochar and EFD&C were only 4.88 wt%and 0.03 wt%,respectively,while the yield from SM@EFD&C catalyst reached 93.14 wt%(89.84 wt%after 7 cycles)under the same conditions,which proved that it had good catalytic activity and stability when used in biodiesel production.This study is of great significance of carbon dioxide emission reduction and environmental protection.