Solvent-Assisted Supramolecular Assembly of Cyclotetrasiloxane– Functionalized Alkynylplatinum(II) Terpyridine Complexes

作     者：Ho-Leung Au-Yeung Sammual Yu-Lut Leung Vivian Wing-Wah Yam 

作者机构：and Department of ChemistryThe University of Hong KongPokfulam RoadHong KongChina 

出 版 物：《CCS Chemistry》 (中国化学会会刊（英文）)

年 卷 期：2019年第1卷第5期

页      面：464-475页

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：This work was also sup-ported by the University Grants Committee Areas of Excellence(AoE)Scheme(AoE/P-03/08) a General Research Fund(GRF)grant from the Research Grants Council of Hong Kong Special Administrative Region,P.R.China(HKU 17304715) 

主　　题：supramolecular cyclotetrasiloxane plati-num solvent effects hydrophobic interaction nanomaterial metal-metal interactions noncova-lent interaction supramolecular polymerization mechanism 

摘      要：Our present study demonstrated and explored the solvent effects on the association mechanism of the supramolecular nanomaterials in a series of cyclo-tetrasiloxane-appended alkynylplatinum(II)terpyri-dine *** the delicate balance of molecular interactions,some of these complexes were found to exhibit molecular association prop-erties,with possible morphological transformation in response to solvent polarities.