Point-to-face contact heterojunctions:Interfacial design of 0D nanomaterials on 2D g-C_(3)N_(4)towards photocatalytic energy applications
作者机构：School of Energy and Chemical EngineeringXiamen University MalaysiaSelangor Darul EhsanMalaysia Center of Excellence for NaNo Energy&Catalysis Technology(CONNECT)Xiamen University MalaysiaSelangor Darul EhsanMalaysia Low Carbon Economy(LCE)Research GroupSchool of Chemical EngineeringUniversiti Sains MalaysiaNibong TebalPulau PinangMalaysia State Key Laboratory of Physical Chemistry of Solid SurfacesCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamenFujianChina Shenzhen Research Institute of Xiamen UniversityShenzhenGuangdongChina
出 版 物：《Carbon Energy》 (碳能源（英文）)
年 卷 期：2022年第4卷第5期
页 面：665-730页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学]
基 金：Ministry of Higher Education,Malaysia,Grant/Award Number:FRGS/1/2020/TK0/XMU/02/1 Guangdong Basic and Applied Basic Research Foundation,Grant/Award Number:2021A1515111019 Hengyuan International Sdn.Bhd.,Grant/Award Number:EENG/0003 Xiamen University Malaysia,Grant/Award Numbers:IENG/0038,ICOE/0001,XMUMRF/2019-C3/IENG/0013,XMUMRF/2021-C8/IENG/0041
主 题：0D/2D heterojunction charge-transfer mechanisms g-C_(3)N_(4)nanosheets heterojunction interface photocatalysis solar-to-energy conversion
摘 要：Green energy generation is an indispensable task to concurrently resolve fossil fuel depletion and environmental issues to align with the global goals of achieving carbon ***,a process that transforms solar energy into clean fuels through a photocatalyst,represents a felicitous direction toward ***-rich metal-free graphitic carbon nitride(g-C_(3)N_(4))is profiled as an attractive photocatalyst due to its fascinating properties,including excellent chemical and thermal stability,moderate band gap,visible light-active nature,and ease of ***,the shortcomings of g-C_(3)N_(4)include fast charge recombination and limited surface-active sites,which adversely affect photocatalytic *** the modification strategies,point-to-face contact engineering of 2D g-C_(3)N_(4)with 0D nanomaterials represents an innovative and promising synergy owing to several intriguing attributes such as the high specific surface area,short effective charge-transfer pathways,and quantum confinement *** review introduces recent advances achieved in experimental and computational studies on the interfacial design of 0D nanostructures on 2D g-C_(3)N_(4)in the construction of point-to-face heterojunction ***,0D materials such as metals,metal oxides,metal sulfides,metal selenides,metal phosphides,and nonmetals on g-C_(3)N_(4)with different charge-transfer mechanisms are systematically discussed along with controllable synthesis *** applications of 0D/2D g-C_(3)N_(4)-based photocatalysts are focused on solar-to-energy conversion via the hydrogen evolution reaction,the CO_(2)reduction reaction,and the N2 reduction reaction to evaluate the photocatalyst activity and elucidate reaction ***,future perspectives for developing high-efficiency 0D/2D photocatalysts are proposed to explore potential emerging carbon nitride allotropes,large-scale production,machine learning integration,and multidiscipli
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