Phase behaviors of ionic liquids attributed to the dual ionic and organic nature

作     者：Chenyu Tang Yanting Wang 唐晨宇;王延颋

作者机构：CAS Key Laboratory of Theoretical PhysicsInstitute of Theoretical PhysicsChinese Academy of SciencesBeijing 100190China School of Physical SciencesUniversity of Chinese Academy of SciencesBeijing 100049China 

出 版 物：《Communications in Theoretical Physics》 (理论物理通讯（英文版）)

年 卷 期：2022年第74卷第9期

页      面：370-384页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(Nos.11774357,22011530390,12047503) the Chinese Academy of Sciences(No.QYZDJ-SSWSYS01) 

主　　题：ionic liquids phase behaviors nanoscale segregation liquid ionic liquid crystal 

摘      要：Ionic liquids(ILs),also known as room-temperature molten salts,are solely composed of ions with melting points usually below 100℃.Because of their low volatility and vast amounts of species,ILs can serve as’green solvents’and’designer solvents’to meet the requirements of various applications by fine-tuning their molecular structures.A good understanding of the phase behaviors of ILs is certainly fundamentally important in terms of their wide *** review intends to summarize the major conclusions so far drawn on phase behaviors of ILs by computational,theoretical,and experimental studies,illustrating the intrinsic relationship between their dual ionic and organic nature and the crystalline phases,nanoscale segregation liquid phase,IL crystal phases,as well as phase behaviors of their mixture with small organic molecules.