Modulated hydrocarbon distribution of gasoline deriving from butene conversion in the presence of syngas

作     者：Yi Ding Feng Jiao Xiulian Pan Xinhe Bao Yi Ding;Feng Jiao;Xiulian Pan;Xinhe Bao

作者机构：Department of Chemical PhysicsUniversity of Science and Technology of ChinaHefei 230026AnhuiChina State Key Laboratory of CatalysisDalian National Laboratory for Clean Energy2011-Collaborative Innovation Center of Chemistry for Energy MaterialsDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina University of Chinese Academy of SciencesBeijing 100049China 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2022年第31卷第10期

页      面：416-421,I0010页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the Ministry of Science and Technology of China (2018YFA0704503) the National Natural Science Foundation of China (Grant Nos. 22002153, 91945302) the Youth Innovation Promotion Association of Chinese Academy of Sciences (2019184) the Natural Science Foundation of Liaoning (2020-BS019) Dalian Science and Technology Innovation Fund (2020JJ26GX028) 

主　　题：Butene utilization Bifunctional catalysts OXZEO Syngas conversion Gasoline 

摘      要：With the expansion of butene production capacity,clean and efficient conversion of mixed butene attracts increasing *** we report direct co-conversion of butene and syngas to highquality gasoline enabled by a bifunctional OXZEO catalyst comprising ZnCrO_(x) oxide and ZSM-5 zeolite.A gasoline selectivity of 71.6% at 98.1% butene conversion and 26.2% CO conversion have been obtained under the reaction conditions of 360℃,3 MPa and 3000 mL g^(-1) h^(-1).The space time yield of gasoline of0.25 g·g^(-1) h^(-1) is ***,the presence of syngas can effectively facilitate iso-paraffin production while hindering the formation of *** is attributed to the prohibited hydrogen transfer aromatization process of butene on ZSM-5 in the presence of *** rthermore,the formation of isomers of gasoline range hydrocarbons is favored because the active intermediates generated from CO/H_(2) activation over ZnCrO_(x) oxide could react with butene over ZSM-5 ***,the product distribution among gasoline range hydrocarbons is modulated with reduced heavy aromatics and improved iso-paraffins,which is desirable for application as *** provides an alternative environmentally friendly technology to utilize still increasing mixed butene.