Anti-Corrosion and Reconstruction of Surface Crystal Plane for Zn Anodes by an Advanced Metal Passivation Technique

作     者：Si Liu Hongxin Lin Qianqian Song Jian Zhu Changbao Zhu Si Liu;Hongxin Lin;Qianqian Song;Jian Zhu;Changbao Zhu

作者机构：State Key Laboratory of Optoelectronic Materials and TechnologiesDepartment of Materials Science and EngineeringKey Laboratory for Polymeric Composite and Functional Materials of Ministry of EducationGuangzhou Key Laboratory of Flexible Electronic Materials and Wearable DevicesSun Yat-Sen UniversityGuangzhou 510275China 

出 版 物：《Energy & Environmental Materials》 (能源与环境材料（英文）)

年 卷 期：2023年第6卷第4期

页      面：166-172页

核心收录：

学科分类：080503[工学-材料加工工程] 0808[工学-电气工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：financialy supported by the National Key R&D Program of China(Grant No.2018YFB0905400) the National Natural Science Foundation of China(Grant Nos.22075331,51702376) the Fundamental Research Funds for the Central Universities(19lgzd02) the Guangdong Pearl River Talents Plan(2019QN01L117) the National Thousand Youth Talents Project of the Chinese Government 

主　　题：anti-corrosion aqueous zinc ion battery interfacial protective layer metal passivation technique reconstruction of surface crystal plane 

摘      要：For the aqueous Zn-ion battery,dendrite formation,corrosion,and interfacial parasitic reactions are major issues,which greatly inhibits their practical *** to develop a method of Zn construction or treatment to solve these issues for Zn anodes are still great ***,a simple and cheap metal passivation technique is proposed for Zn anodes from a corrosion science *** to the metal anticorrosion engineering,the formed interfacial protective layer in a chemical way can sufficiently solve the corrosion ***,the proposed passivity approach can reconstruct Zn surface-preferred crystal planes,exposing more(002)planes and improving surface hydrophilicity,which inhibits the formation of Zn dendrites and hydrogen evolution *** expected,the passivated Zn achieves outstanding cycling life(1914 h)with low voltage polarization(40 mV).Even at 6 mA cm^(−2) and 3 mA h cm^(−2),it can achieve stable Zn deposition over 460 *** treated Zn anode coupled with MnO_(2) cathode shows prominently reinforced full batteries service life,making it a potential Zn anode candidate for excellent performance aqueous Zn-ion *** proposed passivation approach provides a guideline for other metal electrodes preparation in various batteries and establishes the connections between corrosion science and batteries.