Air Stability of Solid‑State Sulfide Batteries and Electrolytes
作者机构：Tianmu Lake Institute of Advanced Energy Storage TechnologiesLiyang 213300JiangsuChina Yangtze River Delta Physics Research CenterLiyang 213300JiangsuChina Beijing Advanced Innovation Center for Materials Genome EngineeringKey Laboratory for Renewable EnergyBeijing Key Laboratory for New Energy Materials and DevicesInstitute of PhysicsChinese Academy of SciencesBeijing 100190China School of Physical SciencesUniversity of Chinese Academy of SciencesBeijing 100049China
出 版 物：《Electrochemical Energy Reviews》 (电化学能源评论（英文）)
年 卷 期：2022年第5卷第3期
页 面：213-258页
核心收录：
基 金：supported by the Key Program-Automobile Joint Fund of the National Natural Science Foundation of China(Grant No.U1964205) the Key R&D Project funded by the Department of Science and Technology of Jiangsu Province(Grant No.BE2020003) the General Program of the National Natural Science Foundation of China(Grant No.51972334) the General Program of the National Natural Science Foundation of Beijing(Grant No.2202058) the Cultivation Project of Leading Innovative Experts in Changzhou City(CQ20210003) the National Overseas High-Level Expert Recruitment Program(Grant No.E1JF021E11) the Talent Program of the Chinese Academy of Sciences,“Scientist Studio Program Funding”from the Yangtze River Delta Physics Research Center and the Tianmu Lake Institute of Advanced Energy Storage Technologies(Grant No.TIES-SS0001)
主 题：Sulfide solid electrolytes Air stability Superionic conductors All-solid-state batteries
摘 要：Sulfides have been widely acknowledged as one of the most promising solid electrolytes(SEs)for all-solid-state batteries(ASSBs)due to their superior ionic conductivity and favourable mechanical ***,the extremely poor air stability of sulfide SEs leads to destroyed structure/performance and release of toxic H_(2)S gas,which greatly limits mass-production/practical application of sulfide SEs and *** review is designed to serve as an all-inclusive handbook for studying this critical ***,the research history and milestone breakthroughs of this field are reviewed,and this is followed by an in-depth elaboration of the theoretical paradigms that have been developed thus far,including the random network theory of glasses,hard and soft acids and bases(HSAB)theory,thermodynamic analysis and kinetics of interfacial ***,the characterization of air stability is reviewed from the perspectives of H2S generation,morphology evolution,mass change,component/structure variations and electrochemical ***,effective strategies for improving the air stabilities of sulfide SEs are highlighted,including H_(2)S absorbents,elemental substitution,design of new materials,surface engineering and sulfide-polymer composite ***,future research directions are proposed for benign development of air stability for sulfide SEs and ASSBs.
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