Molybdenum disulfide(MoS2)-based electrocatalysts for hydrogen evolution reaction:From mechanism to manipulation

作     者：Yao Xu Riyue Ge Jack Yang Jiancheng Li Sean Li Ying Li Jiujun Zhang Jing Feng Bin Liu Wenxian Li Yao Xu;Riyue Ge;Jack Yang;Jiancheng Li;Sean Li;Ying Li;Jiujun Zhang;Jing Feng;Bin Liu;Wenxian Li

作者机构：Institute of MaterialsSchool of Materials Science and EngineeringShanghai UniversityShanghai 200444China School of Materials Science and EngineeringUniversity of New South WalesSydney NSw 2052Australia Materials and Manufacturing Futures InstituteUniversity of NewSouthWalesSydney NSW2052Australia School of Materials Science and EngineeringShanghai UniversityShanghai 200444China InstituteforSustainable EnergyShanghai UniversityShanghai 200444China Collge of Materials Science and EngineeringFuzhou UniversityFuzhou 350108FujianChina Faculty of Materials Science and EngineeringKunming University of Science and TechnologyKunming 650093YunnanChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2022年第31卷第11期

页      面：45-71,I0003页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：financially supported by the National Natural Science Foundation of China(Grant No.51572166) the China Postdoctoral Science Foundation(Grant No.2021M702073) the Rare and Precious Metals Material Genetic Engineering Project of Yunnan Province(Grant No.202002AB080001-1) support from the Program for Professors with Special Appointments(Eastern Scholar:TP2014041)at Shanghai Institutions of Higher Learning 

主　　题：Surface/interface engineering Hydrogen evolution reaction Molybdenum disulfide Mechanisms 

摘      要：Molybdenum disulfide(MoS_(2))-based materials as the non-noble metal catalysts have displayed the potential capability to drive electrocatalytic hydrogen evolution reaction(HER)for green hydrogen production along with their intrinsic activity,tunable electronic properties,low cost,and abundance reserves,which have attracted intensive attention as alternatives to the low-abundance and high-cost platinum-based ***,their insufficient catalytic HER activities and stability are the major challenges for them to become practically ***,the MoS_(2)-based electrocatalysts for HER are comprehensively reviewed to explain the fundamental science behind the manipulations of the crystal structure,microstructure,surface,and interface of MoS_(2) in order to enhance its catalytic performance through changing the electrical conductivity,the number of active sites,surface wettability,and the Gibbs free energy for hydrogen adsorption(ΔGH).Recent studies in surface/interface engineering,such as phase engineering,defect engineering,morphology design,and heterostructure construction,are analyzed to reveal the state-of-the-art strategies for designing and preparing the cost-effective and highperformance MoS_(2)-based catalysts through optimizing the charge transfer,surface-active sites,ΔGH,and surface ***,the perspectives,challenges,and future research directions of HER electrocatalysis are also given to facilitate the further research and development of HER catalysts.