Recent advances of mixed-transition-metal-substituted polyoxometalates

作     者：Zhimin Wang Xing Xin Mo Zhang Zheng Li Hongjin Lv Guo-Yu Yang 

作者机构：MOE Key Laboratory of Cluster ScienceBeijing Key Laboratory of Photoelectroic/Electrophotonic Conversion MaterialsSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 102488China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2022年第65卷第8期

页      面：1515-1525页

核心收录：

学科分类：07[理学] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(21871025,21831001) the Recruitment Program of Global Experts(Young Talents) BIT Excellent Young Scholars Research Fund support from the Analysis and Testing Center of Beijing Instituted of Technology。 

主　　题：polyoxometalates lacunary POM ligands mixed-transition-metal substitution structural diversity catalysis 

摘      要：Polyoxometalates(POMs)have been emerging as one of the most widely-studied interdisciplinary research fields of inorganic chemistry due to their structural diversities and versatile physicochemical properties.The incorporation of transition metals into lacunary POM ligands can lead to the formation of various transition-metal-substituted POMs(TMSPs)with wide potential applications in research areas including medicine,magnetism,functional materials,catalysis,and energy storage.In this review,we summarized the recent advances of mixed-transition-metal-substituted POMs(Mixed TMSPs)with respect to their synthetic strategies,structural diversities,and relevant applications.Finally,a comprehensive outlook of this research area was also prospected.