Recent Advances on Polyoxometalate-Based Ion-Conducting Electrolytes for Energy-Related Devices

作     者：Dongming Cheng Ke Li Hongying Zang Jiajia Chen Dongming Cheng;Ke Li;Hongying Zang;Jiajia Chen

作者机构：Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education at Universities of Jilin ProvinceFaculty of ChemistryNortheast Normal UniversityChangchun 130024China State Key Laboratory of Physical Chemistry of Solid SurfacesDepartment of ChemistryCollege of Chemistry and Chemical EngineeringCollaborative Innovation Centre of Chemistry for Energy MaterialsXiamen UniversityXiamen 361005China 

出 版 物：《Energy & Environmental Materials》 (能源与环境材料（英文）)

年 卷 期：2023年第6卷第2期

页      面：262-274页

核心收录：

学科分类：080801[工学-电机与电器] 0808[工学-电气工程] 07[理学] 08[工学] 070205[理学-凝聚态物理] 0710[理学-生物学] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 0807[工学-动力工程及工程热物理] 0815[工学-水利工程] 080501[工学-材料物理与化学] 0706[理学-大气科学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：financial support from the National Natural Science Foundation of China(No.21871042,21471028,No.21671036,No.21673098,No.21975211) support from the Innovative Research Group Project of NSFC(22021001) the National Key Research and Development Program(2021YFA1502300) Changbai Mountain Scholarship,Natural Science Foundation of Jilin Province(No.20200201083JC) Natural Science Foundation of Department of Education of Jilin Province(No.JJKH20201169KJ) the Fundamental Research Funds for the Central Universities(20720190035) Nanqiang Young Top-notch Talent Fellowship in Xiamen University supported by Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences 

主　　题：energy devices ion conduction polyoxometalates solid-state electrolytes 

摘      要：Solid-state electrolytes have attracted considerable attention in new energyrelated devices due to their high safety and broad application ***(POMs)are a kind of molecular-level cluster compounds with unique *** recent years,owing to their abundant physicochemical properties(including high ionic conductivity and reversible redox activity),POMs have shown great potential in becoming a new generation of solid-state *** this review,an overview is investigated about how POMs have evolved as ion-conducting materials from basic research to novel solid-state electrolytes in energy ***,some expressive POM-based ion-conducting materials in recent years are introduced and classified,mainly inspecting their structural and functional *** that,it is further focused on the application of these ionconducting electrolytes in the fields of proton exchange membranes,supercapacitors,and ion *** addition,some properties of POMs(such as inherent dimension,capable of forming stable hydrogen bonds,and reversible bonding to water molecules)enable these functional POM-based electrolytes to be employed in innovative applications such as ion selection,humidity sensing,and smart ***,some fundamental recommendations are given on the current opportunities and challenges of POM-based ion-conducting electrolytes.