A Novel Ultrafine Ru-B Amorphous Alloy Catalyst for Glucose Hydrogenation to Sorbitol

作     者：Hong Shan LUO Hai Bing GUO He Xing LI Ming Hui WANG Ye Ping XU 

作者机构：Department of ChemistryShanghai Normal UniversityShanghai 200234 

出 版 物：《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期：2002年第13卷第12期

页      面：1221-1224页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：国家自然科学基金(29973025) 上海市自然科学基金 

主　　题：Ru-B amorphous catalyst hydrogenation glucose sorbitol. 

摘      要：An ultrafine Ru-B amorphous alloy catalyst was prepared by chemical reduction with KBH4 in aqueous solution, which exhibited perfect selectivity to sorbitol (~100%) and very high activity during the liquid phase glucose hydrogenation, much higher than the corresponding crystallized Ru-B, the pure Ru powder, and Raney Ni catalysts. The correlation of the catalytic activity to both the structural and surface electronic characteristics was discussed briefly.