Conductive Metal/Covalent Organic Frameworks for CO_(2) Electroreduction

作     者：Chang-Pu Wan Jun-Dong Yi Rong Cao Yuan-Biao Huang Chang-Pu Wan;Jun-Dong Yi;Rong Cao;Yuan-Biao Huang

作者机构：State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China University of Chinese Academy of SciencesBeijing 100049China School of Chemistry and Materials ScienceCollaborative Innovation Center of Chemistry for Energy Materials(iChEM)University of Science and Technology of ChinaHefei 230026China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of ChinaFuzhou 350108China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2022年第41卷第5期

页      面：1-14页

核心收录：

学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by the National Key Research and Development Program of China(Nos.2018YFA0208600,2018YFA0704502) NSFC(Nos.21871263,22071245,22033008) Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China(No.2021ZZ103) 

主　　题：metal-organic frameworks covalent organic frameworks CO_(2)electroreduction reaction conductive frameworks 

摘      要：Porous crystalline metal-organic frameworks(MOFs)and covalent organic frameworks(COFs)are promising platforms for electrocatalytic reduction of CO_(2)(CO_(2)RR)due to their large CO_(2)adsorption uptakes and periodically arranged single active ***,the applications in CO_(2)RR of the traditional MOFs and COFs are greatly limited by their low electron *** recent years,numerous types of MOFs and COFs with high intrinsic conductivity have been rationally designed and successfully constructed,and some of them have been applied in CO_(2)*** this review,the applications of conductive MOFs and COFs in CO_(2)RR have been *** conductive MOFs and COFs can be categorized according to the methods,in which the conductivity is enhanced,such as constructing fullyπ-conjugated backbones,donor-acceptor heterojunction,enhancing theπ-πstacking interactions between organic moieties and/or the introduction of guest molecules.