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Dual Z-scheme Bi_(3)TaO_(7)/Bi_(2)S_(3)/SnS_(2)photocatalyst with high performance for Cr(Ⅵ)reduction and TC degradation under visible light irradiation

Dual Z-scheme Bi3TaO7/Bi2S3/SnS2 photocatalyst with high performance for Cr(Ⅵ) reduction and TC degradation under visible light irradiation

作     者:Jing-Jing Xu Hao-Yu Gu Min-Dong Chen Xue-Ping Li Hong-Wen Zhao Hong-Bin Yang Jing-Jing Xu;Hao-Yu Gu;Min-Dong Chen;Xue-Ping Li;Hong-Wen Zhao;Hong-Bin Yang

作者机构:Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlNanjing 210044China Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologyNanjing 210044China Jiangsu Engineering Technology Research Center of Environmental Cleaning MaterialsNanjing 210044China School of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China Nanyang Technological UniversitySingapore 639798Singapore 

出 版 物:《Rare Metals》 (稀有金属(英文版))

年 卷 期:2022年第41卷第7期

页      面:2417-2428页

核心收录:

学科分类:083002[工学-环境工程] 0830[工学-环境科学与工程(可授工学、理学、农学学位)] 081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学] 

基  金:financially supported by the National Natural Science Foundation of China (No. 51978342) the Open Fund of Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle (No. ES201980195) a project from the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) 

主  题:Photocatalysis Dual Z-scheme Heterojunction Heavy metal Organic pollutant 

摘      要:Ternary direct dual Z-scheme Bi_(3)T_(a)O_(7)/Bi_(2)S_(3)/SnS_(2) photocatalyst was successfully prepared by hydrothermal *** composite photocatalysts exhibited high photocatalytic performance on both Cr(Ⅵ)reduction and tetracycline(TC)degradation under the irradiation of visible *** results manifested that the photogenerated charge transfer efficiency was improved after forming the dual Z-scheme *** a result,the composite catalysts exhibited higher photocat-alytic degradation efficiency than the corresponding single *** apparent rate constant(k)value of the best sample BBS-3 for TC degradation was 0.0403 min^(-1),which was 40 times,8 times,and 18 times higher than that of single *** the k value of BBS-3 for the Cr(Ⅵ)reduction was 0.0249 min^(-1),it was about 23 times,7 times,and 18 times that of single *** experiments indicated that the BBS-3 had good photocat-alytic ***,the possible mechanism on Cr(Ⅵ)reduction and TC degradation was proposed based on the experimental results.

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