Study on the Total Synthesis of 3-Oxo-9β-Acetoxyilicic Acid─The Synthesis of 9β-Acetoxy-3(4),11(13)-Dien-5αH,7αH-12-Eudesmanoic Acid Methyl Ester

作     者：Jiong YANG Zbao Ming XIONG Yong Gang CREN and Yu Lin LI(National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry,ho University, Lanzhou 730000) 

作者机构：Lanzhou Univ Natl Lab Appl Organ Chem Lanzhou 730000 Peoples R China Lanzhou Univ Inst Organ Chem Lanzhou 730000 Peoples R China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1997年第8卷第12期

页      面：0-0页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：The Synthesis of 9 H,7 H-12-Eudesmanoic Acid Methyl Ester Dien-5 Study on the Total Synthesis of 3-Oxo-9 Acetoxyilicic Acid Acetoxy-3 

摘      要：The synthesis of 99-acetoxy-3(4), 11(13)-dien-5αH 7αH-12-eudesmanoic acid methyl ester (2) was achieved from oxycarvone. The key step is the p-toluenesulfonhydrazide assisted reductiv rearrangement reaction