Synthesis and Characterization of Side-Chain Liquid Crystalline Polysiloxanes
侧链液晶聚硅氧烷的合成及表征作者机构:北京理工大学化工与材料学院北京100081
出 版 物:《Journal of Beijing Institute of Technology》 (北京理工大学学报(英文版))
年 卷 期:1997年第6卷第1期
页 面:43-51页
核心收录:
学科分类:0810[工学-信息与通信工程] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0812[工学-计算机科学与技术(可授工学、理学学位)]
基 金:The project supported by the National Natural Science Foundation the Doctoral Programme Foundation of Institution of Higher Education of China
主 题:liquid crystal polysiloxane benzyl ether
摘 要:Side chain liquid crystalline golysiloxanes conta ing biphenyl and benzyl ether mesogen were synthesized by the hydrosilation of poly(methylhydrcsiloxane) with 4-(4-allyloxybenzytoxy)-4 - methoxybiphenyl(M_1),4-(4-allyloxybenzyloxy)-4 -ethoxybiphenyl(M_2),4-(4-allyloxybenzyloxy)-4 - propoxybiphenyl(M_3),4-(4-allyloxybenzyloxy)-4 -butoxybiphenyl(M_4),4-(4-allyloxybenzyloxy)-4 - pentyloxybiphenyl(M_5).The phase behavior of monomeric and polymeric liquid crystals was chararcterized by differential scanning calorimetry and optical polarization *** the monomeric and polymeric liquid crystals exhibit liquid crystal behaviors.