Progress in improving thermodynamics and kinetics of new hydrogen storage materials

作     者：Li-fang SONG Chun-hong JIANG Shu-sheng LIU Cheng-li JIAO Xiao-liang SI Shuang WANG Fen LI Jian ZHANG Li-xian SUN Fen XU Feng-lei HUANG 

作者机构：Materials and Thermochemistrg Laboratory Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China Graduate School of the Chinese Academy of Sciences Beijing 100049 China Faculty of Chemistry and Chemical Engineering Liaoning Normal University Dalian 116029 China Beijing Institute of Technology State Key Laboratory of Explosion Science ＆ Technology Beijing 100081 China 

出 版 物：《Frontiers of physics》 (物理学前沿（英文版）)

年 卷 期：2011年第6卷第2期

页      面：151-161页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 0702[理学-物理学] 

基　　金：Acknowledgements The authors gratefully acknowledged the financial support for this work from the National Basic Research Program of China (973 Program) (Grant No. 2010CB631303)  the National Natural Science Foundation of China (Grant Nos. 20833009  20873148  20903095  50901070  51071146  51071081  and U0734005)  IUPAC (Project No. 2008-006-3-100)  Dalian Science and Technology Foundation (Grant No. 2009AllGX052)  Liaoning BaiQianWan Talents Program (Project No. 2010921050)  and the State Key Laboratory of Explosion Science and Technology  Beijing Institute of Technology (Grant No. KFJJ10-1Z) 

主　　题：ammonia borane hydrogen storage materials hydrides kinetics metal organic frameworks thermodynamics 

摘      要：Hydrogen storage material has been much developed recently because of its potential for proton exchange membrane （PEM） fuel cell applications. A successful solid-state reversible storage material should meet the requirements of high storage capacity, suitable thermodynamic properties, and fast adsorption and desorption kinetics. Complex hydrides, including boron hydride and alanate, ammonia borane, metal organic frameworks （MOFs）, covalent organic frameworks （COFs） and zeolitic imidazolate frameworks （ZIFs）, are remarkable hydrogen storage materials because of their advantages of high energy density and safety. This feature article focuses mainly on the thermodynamics and kinetics of these hydrogen storage materials in the past few years.