Oxygen redox chemistry in lithium-rich cathode materials for Li-ion batteries:Understanding from atomic structure to nano-engineering
Oxygen redox chemistry in lithium-rich cathode materials for Li-ion batteries: Understanding from atomic structure to nano-engineering作者机构:Centre for Clean Energy TechnologySchool of Mathematical and Physical SciencesFaculty of ScienceUniversity of Technology SydneySydneyNSW2007Australia Department of Chemical Engineering and ChemistryEindhoven University of Technology5600MBEindhoventhe Netherlands Fundamental Electrochemistry(IEK9)Forschungszentrum JülichD-52425JülichGermany
出 版 物:《Nano Materials Science》 (纳米材料科学(英文版))
年 卷 期:2022年第4卷第4期
页 面:322-338页
核心收录:
学科分类:0808[工学-电气工程] 07[理学] 08[工学] 070205[理学-凝聚态物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学]
基 金:financial support by the Australian Research Council(ARC)Discovery Project(DP200101249)
主 题:Oxygen redox chemistry Lithium-rich cathode Li-ion batteries Atomic structure Nano-engineering
摘 要:Lithium-rich oxide compounds have been recognized as promising cathode materials for high performance Li-ion batteries,owing to their high specific ***,it remains a great challenge to achieve the fully reversible anionic redox reactions to realize high capacity,high stability,and low voltage hysteresis for lithiumrich cathode ***,it is critically important to comprehensively understand and control the anionic redox chemistry of lithium-rich cathode materials,including atomic structure design,and nano-scale materials engineering ***,we summarize the recent research progress of lithium-rich cathode materials with a focus on redox ***,we highlight the oxygen-based redox reactions in lithium-rich metal oxides,with critical views of designing next generation oxygen redox lithium cathode ***,we purposed the most promising strategies for improving the performances of lithium-rich cathode materials with a technology-spectrum from the atomic scale to nano-scale.