Ternary red phosphorus/CoP2/SiO2 microsphere boosts visible-light-driven photocatalytic hydrogen evolution from pure water splitting

作     者：Chen Yang Yukun Zhu Yiming Liu Hongwei Wang Dongjiang Yang Chen Yang;Yukun Zhu;Yiming Liu;Hongwei Wang;Dongjiang Yang

作者机构：School of Environmental Science and EngineeringState Key Laboratory of Bio-fibers and Eco-textilesShandong Collaborative Innovation Center of Marine Biobased Fibers and Ecological TextilesQingdao UniversityQingdao 266071China College of Materials Science and EngineeringTaiyuan University of TechnologyTaiyuan 030024China 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2022年第125卷第30期

页      面：59-66页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：financial support from the National Natural Science Foundation of China(Nos.51672143,51808303,52102362) Taishan Scholar Program of Shandong Province(ts201712030) Outstanding Youth of Natural Science in Shandong Province(JQ201713) Shandong Provincial Natural Science Foundation(Nos.ZR2021QB022,ZR2021ME012) Applied Basic Research of Qingdao City(Special Youth Project)(19-6-2-74-cg) Qingdao Science and Technology Plan Key Research and Development Special Project No.21-1-2-17-xx State Key Laboratory of Bio-Fibers and Eco-Textiles(Qingdao University)(Nos.ZKT-25,ZKT-26,ZKT-30,ZDKT202105) Science and Technology Support Plan for Youth Innovation of Colleges in Shandong Province(DC2000000961) 

主　　题：Red phosphorus Cobalt phosphide Heterostructure Photocatalytic hydrogen evolution 

摘      要：Red phosphorus(RP) is a promising visible-light-driven semiconductor for photocatalytic hydrogen evolution,but the activity is restricted due to the rapid charge carrier recombination and sluggish surface reaction ***,cobalt phosphide(CoP_(2)) modified RP heterostructure was developed by in situ phosphorization of cobalt oxide from phosphorus *** tuning the amounts of CoP_(2) in the heterostructure,the optimized hybrid exhibited a HER rate reaching 11.79 μmol h^(-1) under visible light illumination,which is 3.5 times higher than that of the RP with Pt as *** was experimentally indicated that the intimate interaction between CoP_(2) and RP gave rise to improved visible light absorption and accelerated photogenerated electron-holes ***,the CoP_(2) as a noble-metal-free cocatalyst could promote the surface hydrogen evolution reaction,which synergetic benefited the photocatalytic hydrogen production activity.