Preparation and characterization of polymer-clay nanocomposite films

作     者：CHEN KeYu WANG ChangAn HUANG Yong LIN Wei 

作者机构：State Key Laboratory of New Ceramics and Fine ProcessingDepartment of Materials Science and EngineeringTsinghua UniversityBeijing 100084China School of Materials Science and Engineering Georgia Institute of Technology771 Ferst Drive NW AtlantaGA 30332USA 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2009年第52卷第12期

页      面：2323-2328页

核心收录：

学科分类：07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：Supported by the National Natural Science Foundation of China (Grant No. 50572044) the 973 Project (Grant No. 2006CB605207-2) 

主　　题：polymer-matrix composites (PMCs) layered structures nanocomposites electrophoretic montmorillonite intercalation 

摘      要：Polymer/clay nanocomposite films were prepared by means of electrodeposition of aqueous suspension including cathodic electrophoretic acrylic resin (CEAR) and Na+-montmorillonite (NMMT). Studies of XRD,SEM and TEM indicated well-dispersed NMMT platelets in the films prepared. The ideal dispersity achieved was thought to be the result of aqueous compatibility between CEAR molecules and NMMT platelets and the result of the water-involved process as well. The modulus and strength of the polymer/clay nanocomposite coatings tested by tensile testing and nano-indentation were effectively improved compared to those of the virgin CEAR film. In addition,the adhesion strength,flexibility and water-resistance represented by Chinese national standard (GB) kept the best grades.