A critical review on nickel-based cathodes in rechargeable batteries

作     者：Lifan Wang Jingyue Wang Leiying Wang Mingjun Zhang Rui Wang Chun Zhan Lifan Wang;Jingyue Wang;Leiying Wang;Mingjun Zhang;Rui Wang;Chun Zhan

作者机构：State Key Laboratory of Advanced MetallurgySchool of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijing 100083China 

出 版 物：《International Journal of Minerals,Metallurgy and Materials》 (矿物冶金与材料学报（英文版）)

年 卷 期：2022年第29卷第5期

页      面：925-941页

核心收录：

学科分类：081702[工学-化学工艺] 0819[工学-矿业工程] 0808[工学-电气工程] 0806[工学-冶金工程] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：financially supported by the China Postdoctoral Science Foundation(No.2021M700396) the National Natural Science Foundation of China(No.52102206) 

主　　题：nickel-based alkaline batteries nickel hydroxide electrodes lithium-ion battery Ni-rich layered oxide cathodes 

摘      要：The 3d transition-metal nickel(Ni)-based cathodes have long been widely used in rechargeable batteries for over 100 years,from Ni-based alkaline rechargeable batteries,such as nickel-cadmium(Ni-Cd)and nickel-metal hydride(Ni-MH)batteries,to the Ni-rich cathode featured in lithium-ion batteries(LIBs).Ni-based alkaline batteries were first invented in the 1900s,and the well-developed Ni-MH batteries were used on a large scale in Toyota Prius vehicles in the *** the same time,however,Sony Corporation commercialized the first LIBs in *** temporally fading as LiCoO_(2) dominated the cathode in LIBs,nickel oxide-based cathodes eventually found their way back to the mainstreaming battery *** uniqueness of Ni in batteries is that it helps to deliver high energy density and great storage capacity at a low *** review mainly provides a comprehensive overview of the key role of Ni-based cathodes in rechargeable *** presenting the physical and chemical properties of the 3d transition-metal Ni,which make it an optimal cationic redox center in the cathode of batteries,we introduce the structure,reaction mechanism,and modification of nickel hydroxide electrode in Ni-Cd and Ni-MH rechargeable *** then move on to the Ni-based layered oxide cathode in LIBs,with a focus on the structure,issues,and challenges of layered oxides,LiNiO_(2),and LiNi_(1−x−y)Co_(x)Mn_(y)O_(2).The role of Ni in the electrochemical performance and thermal stability of the Ni-rich cathode is *** bridging the“oldNi-based batteries and the“modernNi-rich cathode in the LIBs,this review is committed to providing insights into the Ni-based electrochemistry and material design,which have been under research and development for over 100 *** overview would shed new light on the development of advanced Ni-containing batteries with high energy density and long cycle life.