High-Energy Batteries:Beyond Lithium-Ion and Their Long Road to Commercialisation

作     者：Yulin Gao Zhenghui Pan Jianguo Sun Zhaolin Liu John Wang Yulin Gao;Zhenghui Pan;Jianguo Sun;Zhaolin Liu;John Wang

作者机构：Department of Materials Science and EngineeringNational University of SingaporeSingapore 117574Singapore ST Engineering Advanced Material Engineering Pte.Ltd.Singapore 619523Singapore Institute of Materials Research and EngineeringAgency for ScienceTechnology and Research(A*STAR)Singapore 138634Singapore School of Materials Science and EngineeringTongji UniversityShanghai 201804China 

出 版 物：《Nano-Micro Letters》 (纳微快报（英文版）)

年 卷 期：2022年第14卷第6期

页      面：116-164页

核心收录：

学科分类：0808[工学-电气工程] 08[工学] 

基　　金：J.Wang acknowledges the support by MOE,Singapore Ministry of Education(MOE2018-T2-2-095) for research work conducted at the National University of Singapore.Z.L.Liu acknowledges the A*STAR’s Central Research Funds(CRF)Award(Project:SC25/21-111312) Y.Gao acknowledges financial support by ST Engineering Advanced Material Engineering Pte.Ltd.and Singapore Economic Development Board Open access funding provided by Shanghai Jiao Tong University 

主　　题：High energy density Beyond lithium-ion batteries Multivalent-ion batteries Conversion electrode materials Electrolyte 

摘      要：Rechargeable batteries of high energy density and overall performance are becoming a critically important technology in the rapidly changing society of the twenty-first *** lithium-ion batteries have so far been the dominant choice,numerous emerging applications call for higher capacity,better safety and lower costs while maintaining sufficient *** design space for potentially better alternatives is extremely large,with numerous new chemistries and architectures being simultaneously *** include other insertion ions(*** and numerous multivalent ions),conversion electrode materials(***,metallic anodes,halides and chalcogens)and aqueous and solid ***,each of these potential“beyond lithium-ionalternatives faces numerous challenges that often lead to very poor cyclability,especially at the commercial cell level,while lithium-ion batteries continue to improve in performance and decrease in *** review examines fundamental principles to rationalise these numerous developments,and in each case,a brief overview is given on the advantages,advances,remaining challenges preventing cell-level implementation and the state-of-the-art of the solutions to these ***,research and development results obtained in academia are compared to emerging commercial examples,as a commentary on the current and near-future viability of these“beyond lithium-ionalternatives.