Medium-entropy(Me,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)(Me=Y and Ta):Promising thermal barrier materials for high-temperature thermal radiation shielding and CMAS blocking

作     者：Shuaihang Qiu Huimin Xiang Fu-Zhi Dai Hailong Wang Muzhang Huang Chunlei Wan Qing Meng Jiangtao Li Xiaohui Wang Yanchun Zhou Shuaihang Qiu;Huimin Xiang;Fu-Zhi Dai;Hailong Wang;Muzhang Huang;Chunlei Wan;Qing Meng;Jiangtao Li;Xiaohui Wang;Yanchun Zhou

作者机构：Science and Technology on Advanced Functional Composite LaboratoryAerospace Research Institute of Materials and Processing TechnologyBeijing 100076China State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan 430070China School of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China State Key Lab of New Ceramics and Fine ProcessingSchool of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Technical Institute of Physics and ChemistryChinese Academy of SciencesBeijing 100190China Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2022年第123卷第28期

页      面：144-153页

核心收录：

学科分类：080701[工学-工程热物理] 080503[工学-材料加工工程] 08[工学] 0807[工学-动力工程及工程热物理] 0708[理学-地球物理学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China(No.51772275 and No.51972089) Distinguished Young Foundation of Henan Province(No.202300410355)。 

主　　题：Medium-entropy ceramics Thermal barrier coatings Thermal radiation shielding CMAS resistance Infrared absorbance 

摘      要：With continuous enhancement of gas-turbine inlet temperature and rapid increase of radiant heat transfer,thermal barrier coating(TBC)materials with a combination of low thermal conductivity and good high-temperature thermal radiation shielding performance play vital roles in ensuring the durability of metallic blades.However,yttria-stabilized zirconia(YSZ),as the state-of-the-art TBC and current industry standard,is unable to meet such demands since it is almost translucent to high-temperature thermal radiation.Besides,poor corrosion resistance of YSZ to molten calcia-magnesia-alumina-silicates(CMAS)also impedes its application in sand,dust,or volcanic ash laden environments.In order to improve the hightemperature thermal radiation shielding performance and CMAS resistance of YSZ and further reduce its thermal conductivity,two medium-entropy(ME)oxide ceramics,ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)and ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2),were designed and prepared by pressureless sintering of binary powder compacts in this work.ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)presents cubic structure but a trace amount of secondary phase,while ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)displays a combination of tetragonal phase(81.6 wt.%)and cubic phase(18.4 wt.%).Both ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)and ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)possess better high-temperature thermal radiation shielding performance than YSZ.Especially,the high-temperature thermal radiation shielding performance of ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)is superior to that of ME(Y,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)due to its narrower band gap and correspondingly higher infrared absorbance(above 0.7)at the waveband of 1 to 5μm.The two ME oxides also display significantly lower thermal conductivity than YSZ and close thermal expansion coefficients(TECs)to YSZ and Ni-based superalloys.In addition,the two ME oxides possess excellent CMAS resistance.After attack by molten CMAS at 1250℃for 4 h,merely~2μm thick penetration layer has been formed and the structure below the penetration layer is still intact.These results demonstrate that ME(Me,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2)(Me=Y and Ta),especially ME(Ta,Ti)_(0.1)(Zr,Hf,Ce)_(0.9)O_(2),are promising thermal barrier materials for high-temperature thermal radiation shielding and CMAS blocking.