Click synthesis and dye extraction properties of novel thiacalix[4]arene derivatives with triazolyl and hydrogen bonding groups

作     者：Hong-Yu Guo Fa-Fu Yang Zi-Yu Jiao Jian-Rong Lin 

作者机构：College of Chemistry and Chemical EngineeringFujian Normal University Fujian Key Laboratory of Polymer MaterialsFujian Normal University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2013年第24卷第6期

页      面：450-452页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Financial support from the National Natural Science Foundation of China(No.20402002) Fujian Natural Science Foundation of China(No.2011J01031) Project of Fujian Provincial Department of Education(No.JA11044) Program for Excellent Young Researchers in University of Fujian Province(No.JA10056) 

主　　题：Thiacalixarene Synthesis Click chemistry Dye extraction 

摘      要：Using a click reaction between alkynylthiacalix[4]arene and ethyl 2-azidoacetate followed by an ammonolysis with ethanolamine,leucinol and hydrazine hydrate,respectively,three novel thiacalix [4]arene derivatives 4,5 and 6 with triazolyl and hydrogen bonding groups（NH and OH） were synthesized in high *** exhibited excellent extraction capability for six anionic and cationic *** flexible cavity,π-triazole rings and hydrogen bonding groups all play crucial roles in dye complexation.