Selective introduction of surface defects in anatase TiO2 nanosheets for highly efficient photocatalytic hydrogen generation

作     者：Jiang-Yuan Qiu Hua-Zhang Feng Zhao-Hui Chen Shu-Hong Ruan Yan-Ping Chen Ting-Ting Xu Jing-Yun Su En-Na Ha Lu-Yang Wang Jiang-Yuan Qiu;Hua-Zhang Feng;Zhao-Hui Chen;Shu-Hong Ruan;Yan-Ping Chen;Ting-Ting Xu;Jing-Yun Su;En-Na Ha;Lu-Yang Wang

作者机构：College of New Materials and New EnergiesShenzhen Technology UniversityShenzhen 518118China College of Health Scienceand Environmental EngineeringShenzhen Technology UniversityShenzhen 518118China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2022年第41卷第6期

页      面：2074-2083页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China (Nos.21902104 and 21701135) the Natural Science Foundation of Top Talent of Shenzhen Technology University (No.2019108101003) the Foundation for Young Innovative Talents in Higher Education of Guangdong (No.2018KQNCX401) 

主　　题：Defeet engineering Selective reaction Anatase titanium oxide Disorder structure Hydrogen generation 

摘      要：Defect engineering greatly enhances the cat-alytic activity of transition metal semiconductor ***,localized surface defects engineering has been intensively researched,but it still remains challenges on how to tilt the balance to the controllable construction of surface defects rather than bulk ***,we report a facile room-temperature solution processing strategy on(001)facet exposed anatase TiO_(2) nanosheets(ATO),in which localized defects are generated on the surface selectivity with high *** achieve the aspect,lithium-ethylenediamine(Li-EDA)treatment is carried out on(001)facet exposed ATO under a mild *** optimized sample exhibits outstanding photocatalytic H_(2) production rates of 9.28 mmol·g^(-1)·h^(-1) with loading 0.5 wt%Pt as co-catalyst(AM 1.5),which is nearly 7.5 times higher than that of the pristine *** defect engi-neering strategy of ATO photocatalyst will spark the ideas for the defects engineering and semiconductor photocata-lyst,which is with important application prospect in solar energy conversion,including hydrogen generation and carbon dioxide reduction.