Hydrophilic bi-functional B-doped g-C_(3)N_(4) hierarchical architecture for excellent photocatalytic H_(2)O_(2) production and photoelectrochemical water splitting

作     者：Yang Ding Soumyajit Maitra Chunhua Wang Runtian Zheng Meiyu Zhang Tarek Barakat Subhasis Roy Jing Liu Yu Li Tawfique Hasan Bao-Lian Su Yang Ding;Soumyajit Maitra;Chunhua Wang;Runtian Zheng;Meiyu Zhang;Tarek Barakat;Subhasis Roy;Jing Liu;Yu Li;Tawfique Hasan;Bao-Lian Su

作者机构：Laboratory of Inorganic Materials Chemistry(CMI)University of Namur61 rue de BruxellesB-5000 NamurBelgium Namur Institute of Structured Matter(NISM)University of Namur61 rue de BruxellesB-5000 NamurBelgium Department of Chemical EngineeringUniversity of Calcutta92 APC RoadWest BengalKolkata 700009India Department of ChemistryKU LeuvenCelestijnenlaan 200FB-3001 LeuvenBelgium State Key Laboratory of Applied Organic ChemistryKey Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu ProvinceCollege of Chemistry and Chemical EngineeringLanzhou UniversityLanzhou 730000GansuChina State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan 430070HubeiChina Cambridge Graphene CentreUniversity of CambridgeCambridgeCB30DSUK Clare HallUniversity of CambridgeUnited KingdomCB21EWUK 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2022年第31卷第7期

页      面：236-247,I0007页

核心收录：

学科分类：0820[工学-石油与天然气工程] 081702[工学-化学工艺] 0808[工学-电气工程] 081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070304[理学-物理化学(含∶化学物理)] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China(U1663225) the Changjiang Scholar Program of Chinese Ministry of Education(IRT₁5R52) the program of Introducing Talents of Discipline to Universities-Plan 111(B20002)of Ministry of Science and Technology and the Ministry of Education of China and the project “Depollut Air”of Interreg V France-WallonieVlaanderen 

主　　题：Boron doping Hydrophilicity Hierarchically assembled architectures Photocatalytic H_(2)O_(2)production Photoelectrocatalytic water splitting 

摘      要：Graphitic carbon nitride(g-C_(3)N_(4))has attracted great interest in photocatalysis and ***,their poor hydrophilicity poses a great challenge for their applications in aqueous ***,we demonstrate synthesis of a hydrophilic bi-functional hierarchical architecture by the assembly of B-doped g-C_(3)N_(4)*** hierarchical B-doped g-C_(3)N_(4)material enables full utilization of their highly enhanced visible light absorption and photogenerated carrier separation in aqueous medium,leading to an excellent photocatalytic H_(2)O_(2)production rate of 4240.3μM g^(-1)h^(-1),2.84,2.64 and 2.13 times higher than that of the bulk g-C_(3)N_(4),g-C_(3)N_(4)nanoplatelets and bulk B doped g-C_(3)N_(4),*** based on these hierarchical architectures can generate an unprecedented photocurrent density of 1.72 m A cm^(-2)at 1.23 V under AM 1.5 G illumination for photoelectrochemical water *** work makes a fundamental improvement towards large-scale exploitation of highly active,hydrophilic and stable metal-free g-C_(3)N_(4)photocatalysts for various practical applications.