Alternating current electrolysis:A photoredox catalysis mimic and beyond

作     者：Junsong Zhong Chenglin Ding Hyunwoo Kim Terry McCallum Keyin Ye 

作者机构：Institute of Pharmaceutical Science and TechnologyCollege of ChemistryFuzhou UniversityFuzhou 350108China Department of Chemistry and NanoscienceEwha Womans UniversitySeoul 03760South Korea The Canadian Bank Note CompanyOttawaOntario 91758Canada State Key Laboratory of Physical Chemistry of Solid SurfacesXiamen UniversityXiamen 361005China 

出 版 物：《Green Synthesis and Catalysis》 (绿色合成与催化（英文）)

年 卷 期：2022年第3卷第1期

页      面：4-10页

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：This work was supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(No.NRF-2021R1C1C1004605)(H.Kim) the National Natural Science Foundation of China(Nos.22171046,21901041)(K.Y) 

主　　题：Electrochemistry Photoredox catalysis Alternating current electrolysis Green chemistry Selectivity 

摘      要：Alternating current electrolysis(ACE)is an emerging powerful synthetic tool,which principally resembles photoredox catalysis *** periodically alternating polarity feature allows oxidation and reduction processes to take place on the same electrode surface in a well-controlled manner via the fine-tuning of current frequency along with other reaction ***,many challenging transformations in typical direct electrolysis,including constant current electrolysis or constant potential electrolysis,could be achieved via *** recent advances in the organic synthesis using this emerging technology and its advantages over direct electrolysis are highlighted.