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Iron-catalyzed indolo[2,3-c]quinoline synthesis from nitroarenes and benzylic alcohols/aldehydes promoted by elemental sulfur

作     者:Rong Li Shuxin Jiang Haolin Zheng Hanwen Lei Zhi Huang Shanping Chen Guo-Jun Deng 

作者机构:Key Laboratory for Green Organic Synthesis and Application of Hunan ProvinceKey Laboratory of Environmentally Friendly Chemistry and Application of Ministry of EducationCollege of ChemistryXiangtan UniversityXiangtan 411105China Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates(South China University of Technology)Guangzhou 510640China 

出 版 物:《Green Synthesis and Catalysis》 (绿色合成与催化(英文))

年 卷 期:2022年第3卷第1期

页      面:95-101页

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:Financial support from the National Natural Science Foundation of China(Nos.21871226 and 21572194) the Hunan Provincial Natural Science Foundation of China(No.2020JJ5531) the Open Fund of Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates,Guangzhou 510640,China(South China University of Technology)(No.2019B030301003) the Undergraduate Investigated Study and Innovated Experiment Plan from Ministry of Education of China and Hunan Province is gratefully acknowledged 

主  题:Iron-catalyzed Nitro reduction Alcohol oxidation Oxidative annulation Indolo[2,3-c]quinolines 

摘      要:An iron-catalyzed strategy for the rapid synthesis of indolo[2,3-c]quinolines has been *** cascade reaction involving alcohol oxidation,nitro reduction,and oxidative annulation was achieved in a *** present protocol was started from mono-functionalized indoles and readily available benzylic alcohols/aldehydes,affording a variety of functionalized indolo[2,3-c]quinolines in satisfactory yields.

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