Asymmetric Electrochemical Arylation in the Formal Synthesis of(+)-Amurensinine

作     者：Qinglin Zhang Kang Liang Chang Guo 

作者机构：Hefei National Laboratory for Physical Sciences at the MicroscaleDepartment of ChemistryUniversity of Science and Technology of ChinaHefei 230026 

出 版 物：《CCS Chemistry》 (中国化学会会刊（英文）)

年 卷 期：2021年第3卷第12期

页      面：338-347页

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：The authors acknowledge financial support from the National Natural Science Foundation of China(grant nos.21702198 and 21971227) the Anhui Provincial Natural Science Foundation(grant no.1808085MB30) the Fundamental Research Funds for the Central Universities(no.WK2340000090) 

主　　题：asymmetric catalysis electrochemistry Lewis acid catalysis arylation α α-diaryl carbonyl skeletons 

摘      要：Asymmetric electrochemical synthesis has emerged as an attractive and sustainable alternative for the distinctive activation of bond connections in the preparation of diverse enantiomerically enriched targets,including natural products and pharmaceutical ***,we describe the chiral Lewis acid-catalyzed enantioselective electrochemical anodic coupling reaction as a key step in the presented formal synthesis of isopavine alkaloids.