Controlling the aggregation and assembly of boron-containing molecular and polymeric materials

作     者：Daisuke Shimoyama Frieder Jäkle 

作者机构：Department of ChemistryRutgers University-NewarkNewarkNew JerseyUSA 

出 版 物：《Aggregate》 (聚集体（英文）)

年 卷 期：2022年第3卷第2期

页      面：50-59页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：National Science Foundation(NSF) Grant/Award Number:1904791 

主　　题：boron luminescent materials nanostructure self-assembly supramolecular polymers 

摘      要：Boron-containing molecules and polymers are attractive as powerful tunable Lewis acids for small molecule activation and catalysis,as luminescent materials for organic electronic device and(bio)imaging applications,and as smart chemical *** the characteristics of the boron-containing building blocks are attractive in and of themselves,their assembly into higher order supramolecular materials offers access to unique properties and emerging ***,we highlight recent achievements in the field of aggregated organoboron *** discuss how supramolecular interactions can be exploited to precisely control the structure of the assemblies and impact their functions as luminescent materials,recyclable and smart catalyst systems,chemical sensors,stimuli-responsive and self-healing materials.