Selective Oxidation of Methane into Methanol Under Mild Conditions

作     者：LIU Yifeng WANG Liang XIAO Feng-Shou LIU Yifeng;WANG Liang;XIAO Feng-Shou

作者机构：Key Lab of Applied Chemistry of Zhejiang ProvinceDepartment of ChemistryZhejiang UniversityHangzhou310028P.R.China Key Lab of Biomass Chemical Engineering of Ministry of EducationCollege of Chemical and Biological EngineeringZhejiang UniversityHangzhou310027P.R.China Zhejiang Tianlan Environmental Protection Technology Limited CompanyHangzhou310012P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2022年第38卷第3期

页      面：671-676页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：This work was supported by the National Natural Science Foundation of China(No.21932006) 

主　　题：Methane oxidation Metal@zeolite Hydrogen peroxide Methanol 

摘      要：Selective oxidation of methane to methanol under mild conditions has been considered as a dream reaction but suffers from poor efficiency due to the strong C-H bond of methane and easy overoxidation of the methanol *** overcoming these problems,a series of strategies has been developed for improving methanol productivity with oxidants of hydrogen peroxide and even a mixture of oxygen and hydrogen at mild *** achievements in these strategies using effective catalysts,such as supported metal nanoparticles,colloidal metal nanoparticles,and metal@zeolites are briefly ***,the current challenges,future perspectives for preparing active,selective,and stable catalysts,have been *** zeolite fixed metal nanoparticle structure has been found to boost the reaction by benefiting the formation and enrichment of peroxide intermediates,which might guide the development of more efficient catalysts.