Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry

作     者：Hao Wang Hao Wang

作者机构：School of Chemistry and Chemical EngineeringSoutheast UniversityNanjing 211189China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2022年第33卷第8期

页      面：3672-3680页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China(No.21901039) the Natural Science Foundation of Jiangsu Province(No.BK20190327) 

主　　题：Carborane Borylene Carbene Silylene Main group chemistry 

摘      要：Carboranes are a class of polyhedral boron-carbon molecular clusters,they can serve as versatile ligands in stabilizing low-valent main group element compounds,due to their exceptionally thermal and chemical stabilities,easy modifications at the cage carbon vertices,as well as large spherical steric *** carborane-based ligands provide interesting opportunities for the synthesis of low-valent main group element compounds with novel structure and reactivity,which indeed enrich the chemistry of low-valent element main group *** review summarizes the recent advances in the chemistry of lowvalent group 13 and group 14 element compounds supported by carborane-based *** and perspectives in this new and flourishing field are discussed in this review.