Recent Advances in Flame Retardant Bio-Based Benzoxazine Resins

作     者：Hongliang Ding Xin Wang Lei Song Yuan Hu 

作者机构：State Key Laboratory of Fire ScienceUniversity of Science and Technology of ChinaHefei230026China 

出 版 物：《Journal of Renewable Materials》 (可再生材料杂志（英文）)

年 卷 期：2022年第10卷第4期

页      面：871-895页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：We gratefully acknowledge financial support from the National Natural Science Foundation of China(Grant No.22075265) the Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.2021459) 

主　　题：Bio-based benzoxazine curing mechanism thermal stability flame retardancy 

摘      要：Benzoxazines have attracted wide attention from academics all over the world because of their unique ***,most of the production and preparation of benzoxazine resins depends on petroleum resources now,especially bisphenol A-based ***,owing to the environmental impacts,the development of bio-based benzoxazines is gaining more and more interest to substitute petroleum-based *** to petroleum-based benzoxazines,most of bio-based benzoxazines suffer from ***,it is necessary to endow bio-based benzoxazines with outstanding flame *** purpose of this review is to summarize the latest advance in flame retardant bio-based ***,three methods of the synthesis of bio-based benzoxazines are introduced ***,the curing mechanism of benzoxazine and the effect of branched chains on the curing behavior are also discussed and ***,this review focuses on fully bio-based benzoxazines,partly bio-based benzoxazines,and bio-based benzoxazine composite materials in terms of flame retardancy as well as thermal stability and some other special ***,we give a brief comment on the challenges and prospects of the future development of flame retardant bio-based benzoxazines.