Ionic Covalent Organic Framework:What Does the Unique Ionic Site Bring to Us?

作     者：FU Yu LI Yinhui ZHANG Wenxiang LUO Chen JIANG Lingchang MA Heping FU Yu;LI Yinhui;ZHANG Wenxiang;LUO Chen;JIANG Lingchang;MA Heping

作者机构：School of Chemical Engineering and TechnologyXi'an Jiaotong UniversityXi'an 710049P.R.China Petrochemical Research InstitutePetroChinaBeijing 102200P.R.China College of BiologicalChemical Science and EngineeringJiaxing UniversityJiaxing 314001P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2022年第38卷第2期

页      面：296-309页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：supported by the National Natural Science Foundation of China(Nos.22178280,21773223) the Natural Science Basic Research Plan in Shaanxi Province of China(Nos.2020JM-005,2020JQ-017) the Fundamental Research Funds for the Central Universities,China(No.xzy012019027) the Fundamental Research Funds for“Young Talent Support Plan”of Xi'an Jiaotong University,China(No.HG6J001) the“1000-Plan Program”of Shaanxi Province,China 

主　　题：Ionic covalent organic framework Design and construction Various application Structure-function relationship 

摘      要：Ionic covalent organic frameworks featuring both crystallinity and charged sites have arose tremendous attention from scientific community. The adjustable textural structures, well-defined channels and abundant charged sites of ionic COFs facilitate great potential in diverse aspects, such as separation, ion conduction, sensing, catalysis and energy storage. In this review, we first introduced the design and construction of ionic covalent organic frameworks(COFs), and classified them according to the types of charged sites. We focused on the various applications of ionic COFs in diverse fields. The structure-function relationship was also explored in detail. Finally, the opportunities and challenges of ionic COFs were summarized to provide guidance for better design and application of ionic COFs.