Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

作     者：马征 董晓霞 胡玉峰 张柏松 徐长英 刘艳升 MA Zheng;DONG Xiaoxia;Hu Yufeng;ZHANG Bosong;XU Changying;LIU Yansheng

作者机构：Shandong Province Key laboratory of Plant Nutrition and Fertilizer Agriculture Resources and Environment InstituteShandong Academy of Agricultural Science Jinan 250100China State Key Laboratory of Heavy Oil Processing China University of Petroleum Beijing 102249 China 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2013年第21卷第12期

页      面：1370-1375页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China(21176248) 

主　　题：ionic liquid activity coefficients at infinite dilution organic reactions 

摘      要：It is important to know how ILs(ionic liquids)influence organic *** this paper,activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed *** the study on typical organic reactions happened in ILs,such as Diels-Alder,esterification and Friedel-Crafts reaction,the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.