Dimensional Reduction of Eu-Based Metal-Organic Framework as Catalysts for Oxidation Catalysis of C(sp^(3))-H Bond

作     者：Yin Zhang Wei-Dong Yu Cai-Feng Zhao Jun Yan Yin Zhang;Wei-Dong Yu;Cai-Feng Zhao;Jun Yan

作者机构：Junior Education DepartmentChangsha Normal UniversityChangshaHunan 410100China College of ScienceHunan University of Technology and BusinessChangshaHunan 410000China College of Chemistry and Chemical EngineeringCentral South UniversityChangshaHunan 410000China Hunan Institute of Nuclear Agricultural Science and Space BreedingHunan Academy of Agricultural ScienceChangshaHunon 410000China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2022年第40卷第4期

页      面：480-486页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：supported by Changsha Municipal Natural Science Foundation(kq2014164) the Natural Science Foundation of Hunan Province(Grant 2020JJ4684) Science and Technology Innovation Project of Hunan Academy of Agricultural Sciences(2020CX45) 

主　　题：Metal-organic frameworks Heterogeneous catalysis Rare earths Dimensional reduction Selectively oxidize C(sp^(3))-H 

摘      要：Comprehensive Summary Developing new catalysts for highly selectivity and conversion of saturated C(sp^(3))-H bonds is of great *** order to obtain catalysts with high catalytic performance,six Eu-based MOFs with different structural characteristics were obtained by using europium ions and different organic acid ligands,namely Eu-1~***-1,Eu-2 and Eu-3 featured three-dimensional structures,while Eu-4 and Eu-5 featured two-dimensional structures.